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Author list |
Sivan, Sanil E.; Lee, Minhui; Lee, Su-Kyung; Yoon, Ji Woong; Kim, Kiwoong; Hong, Do-Young; Cho, Kyung-Ho; Lee, U-Hwang; Chang, Jong-San; Jung, Jaehoon; Hwang, Young Kyu |
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Abstract |
Oxo-ridged trimeric chromium acetate clusters [Cr3O(OOCCH3)6(H2O)3]NO3 have been encapsulated for the first time in the mesoporous cages of the chromium terephthalate MIL-Cr). The isolated clusters in MIL-Cr) have increased affinity towards propylene compared to propane, due to generation of a new kind of pocket-ased propylene-inding site, as supported by DFT calculations.
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