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Title |
Selective and Quantitative Synthesis of a Linear [3]Catenane by Two Component Coordination-Driven Self-Assembly |
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Author list |
Singh, Jatinder; Kim, Dong Hwan; Kim, Eun-Hee; Singh, Nem; Kim, Hyunuk; Hadiputra, Rizky; Jung, Jaehoon; Chi, Ki-Whan
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Publication date |
2019/06 |
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Citation information |
Chemical Communications, 55, 6866 (2019) |
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DOI |
10.1039/C9CC03336J |
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Graphical Abstract |
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Abstract |
Here we report the synthesis of a linear [3]catenane comprised of three interlocking rings, by coordination-driven self-assembly. Naphthalene-based acceptor A1 and triazole-based donor L1 were utilized for the self-assembly reaction, which facilitated the formation of linear [3]catenane topology through synergistic non-covalent intercycler interactions (π―π, CH―π and CH―N).
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